Sublimation

A sublimation heat engine

Heat engines are based on the physical realization of a thermodynamic cycle, most famously the liquid-vapour Rankine cycle used for steam engines. Here we present a sublimation heat engine, which can convert temperature differences into mechanical work via the Leidenfrost effect. Through controlled experiments, quantified by a hydrodynamic model, we show that levitating dry-ice blocks rotate on...

Graphite Sublimation Tests

Sublimation inside an elastoplastic material.

Thermodynamic and kinetic approaches for sublimation inside elastoplastic material under tensile stress are developed for large strains. Various conceptual problems related to irreversible plastic deformation are addressed for a spherical bubble. They include definitions of the thermodynamic driving forces and activation energies, nontraditional concepts of a critical nucleus, path dependence o...

Freud and Nietzsche on Sublimation

The notion of sublimation is essential to Nietzsche and Freud. However, Freud’s writings fail to provide a persuasive notion of sublimation. In particular, Freud’s writings are confused on the distinction between pathological symptoms and sublimation and on the relation between sublimation and repression. After rehearsing these problems in some detail, it is proposed that a return to Nietzsche ...

The enthalpy of sublimation of cubane

13 The sublimation enthalpy of cubane, a key reference material for force field and quantum mechanical computations, was measured by combining the vaporization enthalpy at T = 298.15 K to the sum of the fusion enthalpy measured at T = 405 K and a solid–solid phase transition that occurs at T = 394 K. The fusion and solid–solid phase transitions were measured previously. A sublimation enthalpy v...